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Quinta Giustiniani en Pádua, in Padua, Veneto, Italy more
The caption, Quinta Giustiniani en Pádua, means Giustiniani farmhouse in Padua; the Giustiniani family were originally in Venice; Padua is some forty kilometres (25 miles) from Venice.
The picture appears to show a very ornate Baroque stone façade with high arches, square pillars and a statue in a niche over the door; there’s a woman holding a baby and another sitting, and there are trees and vines and a ruined Romanesque arch in the foreground.
The index of the book attributes this picture to Emilio Kirchner, which I have taken to be a Portugese spelling of Albert Emil Kirchner, a celebrated German painter who died in 1885.